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Silicone Antifoam and Defoamer Practical Guide

Overview

Silane Coupling Agents Practical Guide

Fundamental Chemistry and Mechanism

Silane Coupling AgentSilane Coupling Agents (SCA) is an organosilane compound featuring two key reactive groups: an organofunctional group (R) and a hydrolyzable group (X) bonded to a silicon atom (Si). Its general structure is R-Si-(X)₃. The hydrolyzable group, often an alkoxy group like methoxy or ethoxy, reacts with moisture to produce silanol groups (Si-OH). These silanol groups then bond with hydroxyl groups on the surface of inorganic materials, such as glass, silica, or metal oxides, forming stable siloxane bonds (Si-O-Substrate).

The organofunctional group (R) is specifically designed to interact with or blend into the organic polymer matrix, such as epoxy, polyester, or rubber. This dual reactivity establishes a strong chemical connection—the “coupling”—between the two different materials. This mechanism is essential for enhancing interfacial adhesion and improving overall material performance.

Silane Coupling Agents primarily enhance the bond between inorganic fillers or reinforcements and organic polymer matrices. (Ref. Silane coupling agents used for natural fiber/polymer composites: A review – ResearchGate) This stronger adhesion leads to several key advantages for the final composite material:

Benefit Description Industrial
Enhanced Mechanical Properties Significant increase in tensile strength, flexural strength, and impact resistance. Allows for lighter, stronger materials in automotive and aerospace applications.
Improved Electrical Properties Reduction in dielectric constant and dissipation factor, especially under wet conditions. Essential for high-performance electronic encapsulation and insulation.
Increased Hydrolytic Stability The stable siloxane bond prevents water from penetrating and weakening the interface. Extends the service life of materials exposed to high humidity or water.
Better Dispersion SCAs can modify the surface energy of fillers, leading to better dispersion in the polymer. Results in a more homogeneous composite with predictable performance.

Ref. A Guide to Silane Solutions: Adhesives and Sealants – AZoM

Silane Coupling Agents (SCAs) act as adhesion promoters, but the term specifically refers to a unique category of organosilane compounds that enhance adhesion through a distinct chemical bridging process. Other adhesion promoters include a wider variety of substances, such as titanates, zirconates, or various primers, which often depend on physical entanglement, hydrogen bonding, or simple acid-base interactions.

The main difference is that SCAs create a covalent bond between inorganic and organic materials, offering a level of durability and hydrolytic stability that most other adhesion promoters cannot match

Silane Coupling AgentsEffectiveness of a Silane Coupling Agents largely depends on its molecular structure, particularly the type of organofunctional group (R) and the length of the alkyl chain (linker) that connects it to the silicon atom.

  • Organofunctional Group (R): This group must be chemically compatible with the polymer matrix. For instance, an epoxy-functional silane, such as γ-glycidoxypropyltrimethoxysilane, works well with epoxy resins. In contrast, an amino-functional silane, like γ-aminopropyltriethoxysilane, is better suited for polyurethanes or phenolic materials. Using an incompatible functional group can lead to poor coupling efficiency.
  • Linker Length: The length of the alkyl chain between the silicon atom and the organofunctional group affects the molecule’s flexibility and mobility at the interface. Longer, more flexible linkers can enhance stress relaxation and durability, while shorter linkers tend to provide greater rigidity.

Selection, Application, and Process

Choosing the right Silane Coupling Agents is essential for formulating composites. This selection process mainly involves aligning the organofunctional group of the silane with the chemistry of the polymer matrix.

Polymer Matrix Recommended Silane Functional Group Example SCA
Epoxy, Phenolic, Polyimide Epoxy, Amino Glycidoxypropyltrimethoxysilane (GPTMS)
Unsaturated Polyester, Vinyl Ester Methacrylate, Vinyl Methacryloxypropyltrimethoxysilane (MPTMS)
Polyurethane, Nylon, Acrylic Amino Aminopropyltriethoxysilane (APTES)
Polyolefins (PE, PP) Vinyl, Mercapto Vinyltrimethoxysilane (VTMS)

SilaneCouplingAgents

Silane Coupling Agents play an important role in nearly every sector of chemical and materials industry, especially when bonding different materials for optimal performance. Here are some key application areas:

  1. Composites: These agents treat glass fibers, carbon fibers, and mineral fillers in reinforced plastics, making them essential for the automotive, construction, and wind energy sectors.
  2. Coatings and Paints: They enhance adhesion, corrosion resistance, and scratch resistance on metal and glass surfaces.
  3. Adhesives and Sealants: Silane Coupling Agents improve bond strength and durability, especially in moisture-cured systems.
  4. Rubber and Tire Industry: They treat silica and clay fillers to enhance abrasion resistance and lower rolling resistance.
  5. Electronics: These agents are used in encapsulation and potting compounds to provide moisture protection and ensure thermal stability.

To effectively treat inorganic fillers with a Silane Coupling Agent, it is crucial to manage several key factors:

  • Filler Surface Chemistry: The filler should have enough surface hydroxyl groups (such as those found in SiO₂ and Al₂O₃) to allow for a reaction with the silanol groups.
  • Moisture Content: Water plays a vital role in the hydrolysis of the silane. Insufficient water can hinder hydrolysis, while excessive water may cause the silane to self-condense, resulting in oligomers that are less effective.
  • pH of the Solution: Hydrolysis is typically accelerated by either an acid or a base. Maintaining an optimal pH (generally between 4 and 5 for most silanes) promotes quick and complete hydrolysis without premature condensation.
  • Concentration and Coverage: The Silane Coupling Agent should be applied in a quantity sufficient to create a monolayer on the filler surface. Over-application can waste resources and negatively affect mechanical properties

Application method for a Silane Coupling Agent depends on the type of inorganic substrate—whether it’s a filler, fiber, or surface—and the final manufacturing process.

Application Method Description Column 3 Column 4
Solution Treatment (Wet) Substrate is dipped or sprayed with a dilute aqueous or organic solution of the hydrolyzed silane. Fibers, large surfaces, pre-treatment of fillers. Consistent coverage with highly effective coupling.
Dry Blending Liquid silane is sprayed directly onto the filler powder during high-speed mixing. Fine particulate fillers (e.g., silica, clay). Cost-effective, single-step process, minimal solvent use.
In-Situ Addition silane is added directly to the polymer/filler mixture during compounding. Fillers in thermoset or thermoplastic processing. Simplifies manufacturing, but requires high shear mixing.

Silane coupling agents are becoming more popular for treating natural fibers, such as wood flour, hemp, and jute, to improve the performance of bio-based polymers. Natural fibers tend to absorb water, making them incompatible with hydrophobic polymer matrices and resulting in low hydrolytic stability. By applying silane treatment, we can decrease the fiber’s water affinity and create strong chemical bonds with the polymer. This process significantly enhances the mechanical properties and water resistance of the resulting bio-composites

Dosage of a Silane Coupling Agents depend on the surface area of inorganic substrate. For most mineral fillers and glass fibers, recommended dosage is between 0.5% and 2.0% by weight of filler. This amount typically creates a complete monolayer on the filler surface. Using less than this optimal range may lead to incomplete coverage and weak bonding. Conversely, applying too much can create a weak layer of unreacted silane oligomers, which can diminish mechanical strength

Technical Performance and Stability

One of key advantages of using a Silane Coupling Agents (SCA) is the enhancement of hydrolytic stability. Water molecules are small enough to infiltrate the interface between untreated inorganic fillers and polymers, which can cause the polymer to separate from the filler. SCAs address this issue by creating strong, water-resistant siloxane bonds (Si-O-Si) with the inorganic surface. These covalent bonds are significantly more durable than the weaker secondary forces, such as van der Waals or hydrogen bonds, that typically govern adhesion in untreated systems.

By shielding the interface from water intrusion, SCAs help maintain the material’s integrity. This protection ensures that mechanical properties remain stable, even after extended exposure to high humidity or immersion in water.

Moisture is a double-edged sword for Silane Coupling Agents. It is absolutely necessary for the initial hydrolysis step, which converts the alkoxy groups to reactive silanol groups. However, high humidity or excessive moisture during the curing or service life of the final product can be detrimental.
  • During Application: Controlled humidity is required for proper silanol formation and subsequent condensation.
  • During Service: While the siloxane bond is highly hydrolytically stable, prolonged exposure to hot, wet conditions can still lead to slow degradation of the interface. This is why the choice of the organofunctional group and the density of the silane layer are crucial for long-term durability.
Silane Coupling Agents are specialized chemicals that require careful handling. Most SCAs are liquids and are classified as irritants, and some are flammable. Key guidelines include:
  • Ventilation: SCAs, particularly those with methoxy groups, release methanol upon hydrolysis, which requires adequate ventilation.
  • Personal Protective Equipment (PPE): Always use appropriate gloves, eye protection, and protective clothing.
  • Storage: SCAs are sensitive to moisture and heat. They must be stored in tightly sealed containers in a cool, dry, and well-ventilated area to prevent premature hydrolysis and polymerization.
  • Disposal: Follow local regulations for the disposal of organosilane compounds and their byproducts. Always consult the product’s Safety Data Sheet (SDS) for specific instructions

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Overview

Silane Coupling Agent Manufacture Top10 in China

Top 10 Silane Coupling Agent Manufacture in China

Silane coupling agents play a crucial role in enhancing adhesion between organic and inorganic materials, making them essential in various industries, including coatings, adhesives, and composites.

China is home to several leading silane coupling agent manufacture, known for their innovation and production capacity. Below is a list of the top 10 silane coupling agent manufacture in China.

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Unveiling the New Face: A Journey of Innovation and Growth

Moment of transformation

We are proud to announce our rebranding as SINOSIL, jointly incorporated sales office by manufacturer, a change that reflects our dedication to innovation, growth, and an unwavering commitment to excellence.

As SINOSIL, we are excited to embark on this new chapter. It signifies our commitment to a future of possibilities and achievements. Thank you for being part of our story.

64212f1af8514ec45dbce82d Sustainable

Water Oil Repellent Agent | C6 Fluoropolymer

Water oil repellent agent C6 is alternative short-china C6 PFC versus long chain C8 PFC, providing sustainable alternatives for many applications, including textiles, leathers based on proven C6 chemistry. Chevell offers high performance properties with improved environmental and biological profiles.

What is C6?

  • C6 fluorinated polymers are proven safe for their intended use.
  • C6 fluoropolymer cannot break down to form PFOA or PFOS.
  • Innovative C6 WOR technology, excellent water oil repellency
  • Full product range to meet all performance demands.

Benefits: Chevell, the industry brand leader for valuable-performance barrier agents, performs listed below

  • Water repellency
  • Oil and grease repellency
  • Alcohol resistance
  • Soil resistance
  • Easy to clean property

Application

Industrial Workwear

Fluorine water oil repellent agent C6 from Chevell is ideal for tough and durable coatings for workwear in contact with oil and dirt such as in the automotive and chemical industries. Fabrics made using Chevell’s C6 repellent products are comfortable to wear and highly durable for industrial laundering.

Outdoor Leisure and Sportswear

Chevell fluorinated C6 water oil repellent provides a waterproof coating for outerwear and footwear designed for activities such as skiing, rambling, mountaineering and sailing. These waterproof characteristics mean it is widely used on tents, awnings and canopies to give protection from the elements.

Medical, Emergency Services

Chevell fluoropolymer C6 water oil repellent is suitable for use on surgical gowns, medical drapes, packs, protective masks in the medical industry.

As the industry leader, Chevell provdie multiple grades of both non-fluorinated and fluorinated( C8, C6 )  water oil repellent that provide excellent water and oil repellency to a variety of surfaces.

Through our well-developed polymer design and polymerization technology along with our comprehensive knowledge of water and oil repellency, our products excel in the marketplace.

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Water oil repellent finishing agent market trend

Silicone Solutions… Boundless Possibilities

What were trends shaping fabric water repellent market?

The fabric water repellent market is experiencing dynamic shifts. Innovations in Water oil repellent finishing agent are paving the way for sustainable and highly functional textiles.

Water oil repellent finishing agent technologies are evolving to meet demands for durability and environmental consciousness. These solutions enhance fabric protection without compromising breathability or comfort.

Advancements in formulation processes are making these agents more efficient, providing better performance against stains, moisture, and oils. The drive towards eco-friendly options also ensures that the future of fabric treatment remains both functional and sustainable.

Sustainable and Eco-Friendly water repellent finishing

There was a growing demand for eco-friendly and sustainable textile water oil repellent finishing agent.

Advanced Technologies of water repellent finishing

Advancements in nanotechnology and polymer science were driving the development of more effective and durable water repellent treatments. Innovations such as superhydrophobic coatings were gaining attention for their ability to create extremely water-repellent surfaces.

Application Specific water repellent finishing agent

The market was witnessing a trend towards fabric water repellents designed for specific applications. For example, Water and Oil repellent tailored for outdoor gear, sportswear, or industrial applications, each optimized for the unique requirements of those use cases.

Durable Water Repellency (DWR) in Apparel

In the apparel industry, there was a focus on durable water repellency (DWR) technologies that could withstand repeated wash cycles. Brands were looking for solutions that provided long-lasting water resistance without compromising the breathability and comfort of fabrics.

Water Repellent Agent

Multifunctional Finishes

Fabric treatments with multifunctional properties, such as stain resistance, UV protection, and antimicrobial features in addition to water repellency, were gaining popularity. This trend was driven by the desire for versatile and high-performance fabrics.

Growth in Outdoor and Sports

The outdoor and sports industries were significant consumers of water repellent fabrics. With an increasing focus on outdoor activities and sports, there was a corresponding rise in the demand for fabrics that could withstand various weather conditions.

SinoSil, an repellent supplier of choice

As the industry leader, SINOSIL provides multiple grades of both non-fluorinated and fluorinated( C8, C6 ) products that give excellent water and oil repellency to a variety of surfaces.
Through our well-developed polymer design and polymerization technology along with our comprehensive knowledge of water and oil repellency, our products excel in the marketplace!

64212f1af8514ec45dbce82d Sustainable

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How to Improve Textile Finishing Efficiency?

Silicone softeners are a crucial component in textile finishing, enhancing the softness and durability of fabrics. To fully grasp the significance of maximizing efficiency in silicone softener application, it’s essential to understand the fundamentals of these products and how they work.

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What is the Mechanism of Silicone Softener?

The mechanism behind silicone softeners lies in their molecular structure. Silicone softeners are composed of silicone-based polymers, which have a unique ability to form a lubricating film on the surface of the fabric fibers. This film reduces the friction between fibers, resulting in a smoother, softer texture.

What Makes Fabric Softener Work?

Fabric softeners, including silicone softeners, work by altering the surface properties of textile fibers. They reduce the friction between fibers, making the fabric feel smoother and softer to the touch. Additionally, fabric softeners can improve the drape and overall comfort of the textile.

What Makes Silicone More Flexible?

Silicone’s flexibility stems from its molecular structure, characterized by the presence of silicon-oxygen (Si-O) bonds. These bonds allow for flexibility while maintaining the stability and durability of the material. In silicone softeners, this flexibility is harnessed to create a soft and pliable feel on textiles.

What is the Mechanism of Softening Effect?

The softening effect of silicone-based softeners primarily occurs through the formation of a micro-thin film on the fabric’s surface. This film reduces inter-fiber friction, resulting in improved softness and flexibility. The silicone softener molecules align themselves on the fabric’s fibers, creating a lubricating layer that imparts a soft hand feel.

In conclusion, understanding the application and mechanism of silicone softeners is essential for textile manufacturers aiming to maximize efficiency in their usage. By selecting the right silicone softener, optimizing dosage, and implementing efficient application methods, manufacturers can achieve consistent, high-quality results in textile finishing. Additionally, knowledge of the underlying science behind silicone softeners can aid in product selection and process improvement.

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Non Fluorinated Water Repellent Agent Type

Non fluorinated water repellent do not contain any fluorocarbons, which have come under scrutiny due to their potential adverse effects on human health and the environment. These chemicals are widely utilized for manufacturing outdoor apparel, upholstery, footwear, and automobile components to provide water repellency without compromising on safety. Some of the significant players in the market are Huntsman Corporation, Daikin Industries, Nicca Chemical, Rudolf GmbH, Texchem UK Ltd, and main product include:

  • Paraffin based Fluorine-Free water repellent
  • Silicone based Fluorine-Free water repellent
  • Acrylic based Fluorine-Free water repellent
  • Polyurethane based Fluorine-Free water repellent
  • Nano-SiO2 based Fluorine-Free water repellent

Paraffin based durable Non fluorinated water repellent are rarely used alone in textiles. Silicone waterproofing agents features with excellent initial and durable (drying/drying) waterproof properties; the fabric surface feels soft after processing; Acrylic based Hydrophobing Agent has excellent processing performance, washability and low cost, acrylics based C0 water repellent are usually compounded with paraffin wax or silicone to improve the feel.

Water Repellent Agent

As the industry leader, Chevell provdie multiple grades of both non-fluorinated and fluorinated( C8, C6 ) products that provide excellent water and oil repellency to a variety of surfaces.
Through our well-developed polymer design and polymerization technology along with our comprehensive knowledge of water and oil repellency, our products excel in the marketplace!

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Silicone fabric softener classification

Development of silicone fabric softener

Modified silicone softeners developed in the late 1970s, many of which have been used in the finishing of fabrics, are currently being researched and developed at home and abroad. This kind of product greatly improves the hydrophilicity, washing durability, shrinkage resistance, etc. of the fabric by introducing various reactive groups such as amino group, epoxy group, polyether, hydroxyl group and the like on the side chain of the siloxane. The group gives the fabric a different style. At present, new products that are being researched and competing at home and abroad are generally divided into three categories: reactive, including amino, epoxy, carboxyl, methacryl and fluoroalkyl; non-reactive, mainly simple Polyether modification; mixed type, such as polyether amino and epoxy modified. The most widely used in textiles is polyether modification, while silicone fabric softener are more modified with amino groups. Most of the products are mixed modified, including a small amount of simple amino group, epoxy group, carboxyl group and fluoroalkyl group. Sex. The functional groups and application properties of several modified silicone softeners are shown in the table below.

2.1 Amino-modified Silicone Softener

The amino-modified silicone softener is a polysiloxane having a side chain or an end group bearing an amino group. The amino group may be a primary ammonia, a secondary ammonia, a tertiary ammonia or an ammonium salt, or may be an aromatic ammonia. The synthesis methods are bulk polymerization and emulsion polymerization. The fabric of the amino-modified silicone softener is obviously improved in elasticity, and the combination with the fiber is very strong, and has a good washing effect, so that it has a soft, smooth and full-bodied, elastic hand, and greatly improves the mechanical mechanism of the fabric. Performance, also has a certain anti-wrinkle, anti-shrinkage effect. The organosilicon with aminoethyl and aminopropyl groups in the amino-modified silicone softener has the best effect.

Amino-modified silicone softeners are easily yellowed under the influence of heat or ultraviolet rays and are therefore not suitable for soft finishing of light-colored fabrics. Currently, such softeners are still improving. The improved method is epoxidation, amidation or secondary amination, etc., to control the degree of modification or to adopt mixed modification, or to form a stable silicone microemulsion.

2.2 Epoxy modified Silicone Softener

According to the reaction type, there are mainly three methods for epoxy-modified silicone oil: hydrosilylation reaction of hydrogen-containing silicone oil with terminal alkenyl epoxy compound; octamethylcyclotetrasiloxane (D4), substituted with epoxy group Polymerization of cyclotetrasiloxane (D4) or the like; other synthetic methods such as condensation reaction of α,ω-dihydroxy silicone oil and epichlorohydrin. The epoxy group has high activity and can crosslink with groups such as hydroxyl group, amino group and carboxyl group on the surface of the fiber to form a stable chemical bond, so that the treated fabric has a durable finishing effect. The epoxy-modified silicone-treated fabric has high stability and softness, but has poor slip and water absorption. Since epoxy is basically very reactive. Therefore, the water absorption of the fabric treated with the epoxy-modified silicone can be improved by grafting a strong water-absorbing group at the end of the epoxy group.

2.3 Polyether modified Silicone Softener

The preparation of the polyether modified silicone softener can be carried out according to the mechanisms of hydrosilylation reaction, esterification reaction, Michael addition reaction, active hydrogen epoxy addition reaction, alcohol hydrogen condensation and siloxane hydrolysis condensation reaction. Technology is maturing. Because of their good suitability, biocompatibility and low glass transition temperature, these polymers have advantages that other surfactants cannot match. The introduction of a water-soluble unsaturated polyether on the side chain of the polysiloxane allows the hydrophobic silicone to be converted into a hydrophilic silicone. The fabric finished by the polyether modified silicone also has good anti-staining and antistatic properties, but the softness and the washing durability are poor. Because of its good compatibility with other finishing agents, it can also be used in the same bath as dyeing. Polyether-epoxy hybrid modified silicone combines the advantages of polyether and epoxy silicone, and at the same time makes up for their respective shortcomings. It is a multifunctional multi-component silicone finishing agent with excellent comprehensive performance.

2.4 Other modified silicone softener

2.4.1 Carboxyl modified silicone softener

In the presence of a platinum catalyst, a carboxyl group-modified silicone can be obtained by an addition reaction of an unsaturated fatty acid with a Si—H bond in a silicone. Carboxyl-modified silicone softeners are chemically reactive and polar, and can be used in natural fiber finishing to bond well with fibers and improve the antistatic and hygroscopic properties of chemical fibers. When used in combination with an amino group or an epoxy-modified silicone, it can improve the soft hand and is not easily peeled off during washing.

2.4.2 Sulfhydryl modified silicone softener

A mercapto-modified silicone can be obtained by a thiourea method or an acetic acid method. Finishing the wool with it gives the wool a durable shrink-proof and lubricity.

2.4.3 Alcohol modified silicone softener

An alcohol-modified silicone can be obtained by polar addition of an unsaturated alcohol to a Si-H bond in a silicone oil or by introducing a hydroxyl group. Such softeners improve the dyeability, heat resistance and water resistance of the fabric.

2.4.4 Ester-modified silicone softener

The ester-modified silicone softener was synthesized by emulsion polymerization using hydrogen-containing silicone oil and acrylate under the action of water-soluble catalyst. The softening agent can make the fabric soft and smooth, and has good elasticity, and is suitable for soft finishing of chemical fiber and its blended fabric with cotton.

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Silicone Softener Classification

Silicone Based Fabric Softener Classification and application

Softener that can adsorb on the surface of textile fibers and smooth the surface of the fibers to change the feel and make the product more comfortable. Among the various auxiliaries of textiles, the variety and dosage of softeners are the first, and Silicone Based Fabric Softener are a kind of softener with superior performance, outstanding effect and wide application. These softeners are emulsions or microemulsions of polysiloxanes and their derivatives, which not only give the fabric a good softness and smoothness, but also impart gloss, abrasion resistance, elasticity, antifouling and wrinkle resistance to the surface of the nonwoven fabric. The non-woven fabric has a slippery style, and this kind of material is non-toxic, does not pollute the environment, and has low cost. It has been widely used in various industries. Silicone Softener products have been developed to date, and can be classified into three types: inactive, active and reactive group modification according to the chemical reactivity and fiber reactivity of the active silicone silicone emulsion.

1. Classification and performance characteristics of Silicone Softener

Silicone Softener

1.1 Inactive Silicone Softener

Such softeners are mainly dimethyl silicone oils, called polydimethylsiloxane (DMPS), referred to as methyl silicone oil. It can impart good softness and heat resistance to fabrics, and its emulsion products include Dow Corning 36, 37 and the like. Because the degree of polymerization is not high, it can not crosslink itself, and does not react to the fiber. The texture, fastness and elasticity of the finished fabric are not ideal, so it can not be directly used as a softener, and must be prepared under the action of an emulsifier. Silicone oil emulsion can be applied to fabrics to increase washfastness, such as DIC Silicon softener 500 from Japan and Perlie SI from Bayer. Such softeners are known as first generation silicone softeners.

1.2 Active Silicone Softener

Such softeners mainly replace the two ends of the dimethyl polysiloxane (DMPS) linear structure with a hydroxyl group (-OH) or a hydroxyl group to make it hydrophilic. An emulsion made of such a terminal hydroxyl-terminated dimethylpolysiloxane, a so-called silicone hydroxy emulsion. There are quite a variety of such products, which can be used as a softener alone, or can be cross-linked with other silicones to form a water-insoluble molecular film on the fibers, so the finished fabric has a certain waterproof and washable. The results are Dow Corning 1111, Ultratex FSA from Ciba Geigy, Switzerland. Such softeners are second generation silicone softeners. According to the different surfactants used in the preparation, it can be divided into several types of cationic, anionic, nonionic and complex ions. It can be selected according to the type of fabric.

1.3 Modified Silicone Softener

These softeners introduce other reactive groups on the silicone molecular chain, which have special functions to meet the needs of high-grade finishing of various fabrics, improve the antistatic, oil and hydrophilic properties of the fabric, and make the chemical fiber fabric have Many advantages of natural fabrics have become a third-generation silicone soft finishing agent with special functions.

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