Foam Control

UV Inkjet Dispersant, Photoresist & Conductive Paste Additive

Coating Defoamer

In demanding sectors like UV inkjet inks, microlithography photoresists, and electronic chemicals, standard additives often fall short. Formulators frequently struggle with critical issues such as post-thickening, ink gelation, development residue, and severe pigment agglomeration. To address these bottlenecks, SINOSIL delivers a portfolio of high-purity UV Inkjet dispersant, Photoresists Silicone-free Leveling Agent, Graphene Dispersion in NMP for Battery Pastes and Conductive Carbon Black Slurry Additives, engineered to solve complex formulation challenges—from nanoparticle stabilization to interfacial wetting—enabling the next generation of electronic and coating technologies.

Performance requirements for dispersant in UV inkjet ink significantly exceed those of traditional industrial coatings and inks. Beyond critical pigment color development and viscosity reduction efficiency, most demanding technical challenges include achieving long-term storage stability in solvent-free or low-monomer systems, ensuring reliable jetting performance without printhead clogging, and maintaining precise stabilization of nano-scale particle sizes. Currently, industry selection of suitable dispersant is highly specialized and limited, as many conventional chemistries are prone to post-thickening or catastrophic gelation during storage.

1. Dispersion Solutions for White Pigment Pastes: 9102P and 9213

To meet rigorous demands of Titanium Dioxide (TiO₂) dispersion in UV inkjet systems, SINOSIL offers two high-performance dispersant with specialized functional profiles:

  • 9102P: A 100% active copolymer UV inkjet dispersant featuring acidic phosphate ester groups (Acid Value: 50-70 mg KOH/g). Engineered for broad compatibility, it delivers exceptional viscosity reduction across more than 90% of standard UV resin systems. In a benchmark formulation of 75% TiO₂ and 3% dispersant, 9102P achieved an initial viscosity of approximately 3,600 mPa·s. Following a 7-day accelerated heat-aging test at 50°C, viscosity remained stable below 4,000 mPa·s with zero thixotropy and consistent, smooth flow. Because its molecular structure is amine-free, it eliminates risk of yellowing after UV curing, making it the preferred solution for high-purity white pastes.

  • 9213: A structured styrene-maleic anhydride (SMA) copolymer synthesized via controlled polymerization technology, act as UV inkjet dispersant. This 100% active dispersant incorporates both amine and carboxyl functionality, providing strong anchoring affinity for both organic and inorganic pigments. In identical TiO₂ test formulations, 9213 achieved even lower viscosity profiles (1,600 mPa·s initially, stabilizing at 1,800 mPa·s after heat aging). While its amine content is processed to minimize reactivity, a slight potential for yellowing exists; consequently, it is best utilized as a “universal” dispersant for integrated ink sets that include organic pigments and carbon black.

  • Particle Size Stability: Both dispersant consistently maintain TiO₂ particles at a D50 of approximately 200 nm, ensuring reliable jetting performance and meeting stringent particle size distribution requirements of UV inkjet.

2. Dispersion Solutions for Organic Pigments and Carbon Black: 9213

Primary technical challenge in dispersing organic pigments (such as PR254, PY150, PB15:3) and specialty carbon blacks (such as FW200) for UV inkjet applications is maintaining long-term viscosity stability and preventing gelation. SINOSIL evaluated performance of 9213 through rigorous 80°C water bath heat-storage testing:

  • Accelerated Aging Results: In black (FW200) and red pigment pastes, 9213 maintained a non-thixotropic, gel-free state with virtually no viscosity increase even after two weeks of storage at 80°C.

  • Competitive Performance Benchmark: In contrast, conventional polyurethane-based UV inkjet dispersant (such as 16 series) reached a complete gel state within only two days under identical thermal stress conditions.

  • Proven Reliability: These results confirm that controlled polymer architecture of 9213 effectively maintains pigment particles in a de-flocculated state under extreme conditions. This significantly enhances shelf-life and processing latitude of ink while delivering consistent color development, high gloss, and superior stability across diverse color palettes, including black, blue, and yellow.

Photoresist manufacturing process involves several highly sophisticated stages—including coating, exposure, development, etching, and high-temperature curing—placing technical performance requirements on additives that far exceed those of industrial coatings. In strategic collaboration with key customers, SINOSIL engineered E0321 silicone-free leveling agent, a high-performance solution specifically designed to address following critical industry challenges:

  • Elimination of Development Residue: Various leveling agent can result in different degrees of residual film during development and cleaning phases. In rigorous comparative evaluations, E0321 demonstrates zero residue performance, ensuring absolute substrate cleanliness essential for downstream processing.

  • Optimized Surface Smoothness: Conventional leveling agent often fail to fully discharge micro-bubbles, leading to excessive surface roughness after cure. Through advanced molecular architecture, E0321 eliminates factors that stabilize foam, resulting in a perfectly uniform and planar surface (validated through high-resolution 45° and 90° microscopic imaging).

  • Prevention of Mura Defects: Thickness variations stemming from inadequate leveling often manifest as “whitening” or “Mura” defects during high-precision optical inspection. E0321 delivers superior leveling efficiency, effectively eliminating these coating irregularities.

  • Adhesion and Chemical Resistance: Maintains critical adhesion balance between photoresist and substrate. Furthermore, its performance properties remain stable even when subjected to aggressive developers and specialized cleaning agents.

Featuring 100% active content, E0321 is ideal leveling agent for PSPI (Photosensitive Polyimide) photoresist systems where exceptional cleanliness, surface uniformity, and broad processing latitude are mandatory.

The high polarity and transparency requirements of UV resins make it difficult to find additives that do not cause haze or excessive foaming.

1. Low-Foaming Anti-Cratering Leveling Agent: 6013 & 6023

  • 6013: A 100% active polyether-modified siloxane, act as UV leveling agent. It provides excellent substrate wetting and anti-cratering performance while significantly reducing foam stabilization tendencies. Testing in solvent-free UV systems demonstrates minimal micro-foam after high-speed dispersion, with total air release within 40 minutes, ensuring exceptional film transparency. Its anti-cratering capability outperforms conventional leveling agents, making it ideal for thin films and sensitive substrates.

  • 6023: A 100% active acrylate-modified polysiloxane act as UV leveling agent. While structurally similar to 6013, it contains functional double bonds that participate in UV cross-linking. This ensures long-lasting surface slip and durability without compromising recoatability. While its anti-cratering strength is slightly lower than 6013, it is preferred solution for applications requiring permanent surface performance.

2. Universal High-Penetration Wetting Agent: 2405

2405 is a 100% active polyether-modified siloxane wetting agent engineered to resolve traditional trade-off between low surface tension and excessive foaming:

  • Ultra-Low Surface Tension: Reduces static surface tension to as low as 20.4 mN/m—approaching theoretical limit for silicone wetting agent—providing superior resistance to craters and edge-pulling.

  • Minimal Foaming Profile: Whether in aqueous, solvent-free UV, or solvent-borne systems, it exhibits ultra-low foam or even self-defoaming characteristics. This eliminates common surface defects such as “pinholes” or “dark bubbles” typically caused by stabilized foam in traditional wetting agent.

  • Superior Pore Penetration: Specifically optimized for wood coatings and open-pore finishes, it significantly enhances wetting into deep pores, effectively reducing caoting times.

3. High-Compatibility UV Defoamer: 5980

5980 is a 100% active, silicone free defoamer, provide following features for UV inkjet system:

  • Exceptional Compatibility: Maintains absolute clarity in varnishes and overprint coatings, making it ideal for high-transparency applications such as luxury packaging and silver/gold cardstock printing.

  • High-Efficiency De-aeration: Optimized for high-speed screen printing, it facilitates rapid air release to prevent foam-related defects caused by increased mechanical speeds.

  • Zero “Oil Spots”: As silicone free defoamer, it eliminates risk of craters, “fish-eyes,” or oil spots often associated with incompatible silicone defoamer.

Graphene Dispersant in NMP Systems: 9250

9250 is a 100% active high-molecular-weight copolymer functionalized with pigment-affinic groups. This additive is specifically engineered to optimize storage stability of graphene dispersions within N-Methyl-2-Pyrrolidone (NMP) solvent systems:

  • Exceptional Stability Profiles: In laboratory evaluations, a graphene slurry (approx. 4.5% solids content) dispersed with 9250 showed virtually no sedimentation after 7 days. Analysis revealed consistent solid levels between the top layer (4.53%) and the bottom layer (4.91%).

  • Performance Benchmark: In contrast, conventional dispersants (such as 9242) exhibited severe phase separation under identical conditions, with top layer solids dropping to 0.35% and bottom layer reaching 5.67%.

  • Broad Formulation Latitude: Leveraging its unique macromolecular architecture and multi-solvated segments, 9250 offers excellent versatility across aqueous, alcohol-based, and co-solvent systems. It is also highly effective in organic/inorganic co-grinding processes, delivering superior color consistency.

Aqueous Acetylene Black Dispersant: 9300

9300 is a 100% active polymeric dispersant developed to overcome significant technical hurdles associated with dispersing high-surface-area acetylene black:

  • Advanced Viscosity Control: In formulations featuring 20% acetylene black and 10% dispersant, 9300 delivers an ultra-low, water-thin viscosity profile while maintaining a foam-free state.

  • Proven Competitive Advantage: Comparative testing indicates that alternative chemistries—including polyether, styrene-maleic anhydride (SMA), polyurethane, and standard controlled polymerization types—fail to effectively stabilize acetylene black at these loading levels.

  • High-Pigment Loading Performance: 9300 is equally proficient in dispersing high-color carbon blacks (such as FW200). It maintains low viscosity even at 20% concentrations, providing manufacturers with enhanced color development, water resistance, and superior gloss.

Technical Support & External Resources

For further reading on chemical standards and additive technologies mentioned in this report, visit following professional resources:

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Industrial Coating Defoamer Effective Selection Guide

Coating Defoamer

Waterborne industrial coatings are clear choice for a greener future, but their diverse resin chemistries bring equally diverse foam challenges. Moving beyond generic selection by defoamer chemistry, we now match solutions directly to your resin system. Backed by advanced visualization and digital evaluation technologies, we provide targeted, high-performance coating defoamer strategies for major resin families.

  • System Profile:​ Widely used in general metal protection and appliance finishes. Some high-water-resistance grades can be harder to defoam.
  • Core Coating Defoamer & Benefit:
    • P401W:​ An highly effective deaerator for high-viscosity, hard-to-defoam emulsions. It rapidly eliminates microfoam with minimal impact on water resistance and gloss.
    • 422 / 424:​ Medium-strength, concentrated defoamers offering good compatibility for standard emulsions.
    • 437:​ An emulsion-type defoamer for the let-down stage, providing excellent bubble breaking and foam suppression.
  • Application Case:​ In a CR-3090 emulsion system, adding 0.2% P401W at grind combined with 437 achieved a bubble-free wet film thickness of 275 μm, with minimal gloss loss.
  • System Profile:​ Used in demanding applications like agricultural and construction equipment. Challenges include reaction bubbles during curing and high film build, where microfoam gets trapped.
  • Core Coating Defoamer & Advantage:
    • P401W:​ Add at grind for powerful deaeration, inhibiting reaction bubble formation.
    • 402W:​ A deaerator specialized in merging microfoam for rapid rise to the surface.
    • 437:​ A fast bubble breaker for surface foam with outstanding foam suppression.
    • 4222:​ A concentrated defoamer balancing efficiency and compatibility, ideal for systems sensitive to cratering.
  • Application Case:​ A hydroxy dispersion system using a combination of 4222 (grind), 402W, and 437 (let-down) achieved a 225 μm bubble-free wet film, high gloss, and excellent adhesion, outperforming single-defoamer solutions.
  • System Profile:​ High-temperature bake finishes (140–180°C) requiring exceptional clarity, gloss, and intercoat adhesion. Silicone defoamers can fail at high temperatures, harming adhesion.
  • Core Coating Defoamer & Advantage:
    • 432:​ A 100% active, silicone-free defoamer. Its novel polymer/hydrophobic particle synergy offers strong defoaming, excellent heat resistance (stable at 180°C), and no adhesion loss.
    • 455:​ A highly compatible, silicone-free defoamer for ultra-high clarity applications like inks and thin films.
  • Application Case:​ In a water-soluble acrylic-amino bake system, 0.3% 432 delivered superior gloss (97.9/98.1 at 20°/60°) compared to the control, with no adhesion issues post-bake.
  • System Profile:​ Used in plastic, leather, and textile coatings where supreme compatibility and clarity are critical. Some applications require a defoamer particle size <300 nm for filtration.
  • Core Coating Defoamer & Advantage:
    • HOS 432:​ A compatible, silicone-free defoamer for the grind stage.
    • 4343 / 455:​ Emulsion-type defoamers. 455 contains no hydrophobic particles for finer particle size, ideal for high-clarity systems and strict filtration.
  • System Profile:​ High-PVC primers and mid-coats with high viscosity and film build. Foam, especially trapped microfoam, severely impacts anti-corrosion performance.
  • Core Coating Defoamer & Benefit:
    • P401W:​ Strong deaerator for grind stage.
    • 402W + 437:​ A synergistic let-down combo. 402W tackles microfoam, 437 breaks surface foam, ensuring a dense, bubble-free film.
  • Application Case:​ In an epoxy system, the 402W + 437 combination completely eliminated subsurface and surface bubbles, as confirmed by cross-section analysis.
  • System Profile:​ Used in general metal protection; sensitive systems requiring defoamers with excellent compatibility.
  • Core Coating Defoamer & Benefit:
    • 424:​ Concentrated defoamer for the grind stage.
    • 435:​ Emulsion-type defoamer for the let-down stage, balancing defoaming and compatibility.

Gain deeper insights into the chemistry of waterborne coating formulations via the American Coatings Association

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Silicone Antifoam and Defoamer Practical Guide

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